Strategies for rational design of polymer-based solid electrolytes for advanced lithium energy storage …
For polymer-based electrolytes, the relationship between temperature and ion conductivity follows two dominant conduction mechanisms: namely, Arrhenius or Vogel-Tammann-Fulcher (VTF) model. The well-known Arrhenius model, given in Eq. (1): (1) σ = σ 0 e x p (− E a k B T) where σ o, E a and k B are the pre-exponential factor, activation …